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| Funder | Engineering and Physical Sciences Research Council |
|---|---|
| Recipient Organization | University of Exeter |
| Country | United Kingdom |
| Start Date | Sep 30, 2024 |
| End Date | Mar 30, 2028 |
| Duration | 1,277 days |
| Number of Grantees | 2 |
| Roles | Student; Supervisor |
| Data Source | UKRI Gateway to Research |
| Grant ID | 2921380 |
Quantum batteries represent the next frontier in energy storage, leveraging the principles of quantum mechanics to revolutionize battery technologies. Unlike traditional batteries reliant on chemical reactions, quantum batteries tap into the unique properties of quantum systems, such as superposition and entanglement, to store and access energy. This PhD studentship will focus on experimental investigations into quantum batteries using novel 2D materials.
The PhD researcher will investigate the feasibility and potential of using a range of 2D materials, including germanene, silicene, SiGe heterostructures, and Metal-Organic Frameworks (MOFs), for quantum batteries. Silicene, germanene, and SiGe are of interest due to their distinct electronic properties, which offer opportunities for quantum-enhanced energy storage.
These materials, analogous to graphene but composed of silicon and germanium atoms, demonstrate quantum spin Hall effects, enabling the realization of topologically nontrivial electronic structures. Leveraging these effects, we will develop quantum batteries with enhanced charge transport properties and improved energy efficiency. SiGe heterostructures, composed of alternating layers of silicon and germanium, exhibit promising quantum interference effects and modulated doping characteristics, presenting possibilities for tailored charge transport pathways within battery devices.
The precise manipulation of the properties of these 2D materials through controlled synthesis and structural engineering provides avenues for optimizing battery performance and exploring novel approaches to quantum energy storage. Moreover, we will investigate the potential of 2D MOFs within quantum battery systems. These materials offer high surface area for enhanced charge storage, potential for tailored pore size and chemistry to facilitate selective ion transport, and opportunities for confinement effects within their layers to promote quantum effects at the nanoscale.
The versatility of 2D MOFs allows for functionalization with different groups, enabling the introduction of additional functionalities for enhancing charge transport properties. Methodology:
Material Synthesis and Characterization: We will synthesize high-quality germanene and silicene materials using state-of-the-art techniques, such as chemical vapor deposition and electrochemical exfoliation. Comprehensive characterization, including atomic force microscopy, scanning electron microscopy, and Raman spectroscopy, will be conducted to assess material quality and structural integrity.
Quantum Spin Hall Effect Studies: We will conduct detailed investigations into the behaviour of these materials such as measuring the spin polarization of electrons using techniques like magneto-transport measurements in the presence of a magnetic field.
Device Fabrication and Testing: Utilizing the synthesized 2D materials, we will fabricate prototype quantum battery devices. These devices will incorporate innovative designs to exploit the unique properties of these materials for energy storage. Electrical and electrochemical characterization will be performed to evaluate their performance metrics, including energy density, charge/discharge rates, and cycle stability.
The expected outcomes of this research encompass a comprehensive understanding of the quantum effects in novel 2D materials, elucidating their significance in energy storage. Through the development of prototype quantum battery devices leveraging 2D materials, particularly silicene, Si/SiGe and MOFs, we anticipate demonstrating enhanced energy storage capabilities compared to conventional batteries.
University of Exeter
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